Hello,
You can download the Riffworks application from our software downloads page at http://line6.com/software/ and burn it onto a blank disc or transfer ti onto a flash drive. A 1 GB drive should be big enough. You'll also want to do the same for Line 6 Monkey.
After you have installed Monkey and Riffworks onto your new machine, run Line 6 Monkey with your device connected and download any drivers you need for your device.
You'll also want to perform a refresh in Line 6 Monkey to re-authorize your Riffworks key. Check out the following FAQ to learn how to do that.
http://line6.com/community/docs/DOC-4738
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Line6Miller