Option 1: In global settings, set your volume know to control 1/4 out. This will enable you to change your monitor volume without affecting the XLR output volume. The XLR's are now fixed and volume must be controlled @ FOH (as long as you dont change the overall output level on the output block)
Option 2: Different output levels can also be achieved by creating multiple output lines / parallel lines. 1 for 1/4 set the output block to whatever you like and 2nd output to XLR again the output block set to whatever volume you desire.